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Diesel engine exhaust aftertreatment components, especially the diesel particulate filter (DPF), are subject to various modes of degradation over their lifetimes. One particular adverse effect on the DPF is the significant rise in pressure drop due to the accumulation of engine lubricant-derived ash which coats the inlet channel walls effectively decreasing the permeability of the filter. The decreased permeability due to ash in the DPF can result in increased filter pressure drop and decreased fuel economy. A unique two-step approach, consisting of experimental measurements and direct numerical simulations using ultra-high resolution 3D imaging data, has been utilized in this study to better understand the effects of ash accumulation on engine aftertreatment component functionality.

Ash, primarily derived from diesel engine lubricants, accumulates in diesel particulate filters directly affecting the filter's pressure drop sensitivity to soot accumulation, thus impacting regeneration frequency and fuel economy. After approximately 33,000 miles of equivalent on-road aging, ash comprises more than half of the material accumulated in a typical cordierite filter. Ash accumulation reduces the effective filtration area, resulting in higher local soot loads toward the front of the filter. At a typical ash cleaning interval of 150,000 miles, ash more than doubles the filter's pressure drop sensitivity to soot, in addition to raising the pressure drop level itself. In order to evaluate the effects of lubricant-derived ash on DPF pressure drop performance, a novel accelerated ash loading system was employed to generate the ash and load the DPFs under carefully-controlled exhaust conditions.

While metal fiber filters have successfully shown a high degree of particle retention functionality for various sizes of diesel engines with a low pressure drop and a relatively high filtration efficiency, little is known about the effects of lubricant-derived ash on the fiber filter systems. Sintered metal fiber filters (SMF-DPF), when used downstream from a diesel engine, effectively trap and oxidize diesel particulate matter via an electrically heated regeneration process where a specific voltage and current are applied to the sintered alloy fibers. In this manner the filter media essentially acts as a resistive heater to generate temperatures high enough to oxidize the carbonaceous particulate matter, which is typically in excess of 600°C.

An aqueous urea solution is used as the source of ammonia for selective catalytic reduction (SCR) of NOx to reduce the emissions of NOx in the exhaust of diesel vehicles. However, the decomposition of urea into ammonia is not always complete, resulting in solid urea deposit formation in the decomposition tube or on the SCR catalyst. These solid deposits can impede the flow of the exhaust gases (and uniformity of NH3 supply) and reduce SCR catalyst performance over time. To minimize the formation of urea deposit and to meet EPA NOx emission regulations, it is important to understand the chemistry of formation or removal of the deposit in the decomposition tube and SCR catalyst. In this report, IR spectroscopy, UV-visible spectroscopy, thermogravimetric analysis and elemental analysis have been used to determine the chemical composition of the solid urea deposits formed by the thermal decomposition of urea.

All high-pressure exhaust gas recirculation (EGR) coolers become fouled during operation due to thermophoresis of particulate matter and condensation of hydrocarbons present in diesel exhaust. In some EGR coolers, fouling is so severe that deposits form plugs strong enough to occlude the gas passages thereby causing a complete failure of the EGR system. In order to better understand plugging and means of reducing its undesirable performance degradation, EGR coolers exhibiting plugging were requested from and provided by industry EGR engineers. Two of these coolers contained glassy, brittle, lacquer-like deposits which were analyzed using gas chromatography-mass spectrometry (GC-MS) which identified large amounts of oxygenated polycyclic aromatic hydrocarbons (PAHs). Another cooler exhibited similar species to the lacquer but at a lower concentration with more soot.

Although designed for the purpose of reducing engine-out Particulate Matter (PM) emissions to meet or exceed mandated emissions regulations, the particulate filter also incurs a fuel economy penalty. This fuel penalty is due to the increased exhaust flow restriction attributed to the PM accumulated in the filter, in addition to fuel consumed for active regeneration. Unlike the soot which may be oxidized through the regeneration process, incombustible material or ash continues to build-up in the filter following each regeneration event. Currently pressure- and model-based controls are used to provide an indirect estimate of the loading state of the particulate filter, in order to manage the filter operation and determine when to regenerate the filter. The challenges associated with pressure- and model-based particulate filter control over real-world operating conditions are well-known.